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Chem. , Perkin Trans. 1 , 1980, 7 38. L. R . Orosko and 0. S . Chizhov, Bioorg. K h i m . , 1 9 8 0 , 6 , 1 3 2 1 (Chem. , 1980,93, 239 799). 36 Ethers and Anhydro-sugars 37 Aralkyl Ethers. -Barton and his co-workers have reported a new method of 0-benzylation by sequential treatment of the alcohol with Vilsmeier salt [Me2fi=C(Ph)C1 Cl-1 and sodium telluride. Examples in the carbohydrate field are given, but the method does not appear to have any outstanding advantages over the usual procedures.

Fugedi, A. Liptdk, P. Ndndsi, and A. Neszmelyi, Curbohydr. , 1980, 80, 233. 46 H. A. Nunez and R. Barker, Biochemistry, 1980, 1 9 , 4 8 9 . 47 P. Kovdc and E. Petrdkovd, Chem. Zvesti, 1980, 34, 537. 4 8 P, K O V ~ C Collect. , Czech. Chem. , 1980,45, 892. 49 M. Claeyssens, R. D. Brown, F. Deleyn, and C. K. de Bruyne, J . , Nucleosides, Nucleotides, 1980, 7 , 2 0 3 . 50 Considerable attention has been given to the preparation of L-rhamnosecontaining disaccharides, and several rhamnosylating agents have been used.

Rao and N . Roy, Indian J. C h e m . , S e c t . , 1 9 8 0 , 1 9 , 1 6 1 (Chem. , 1 9 8 0 , 9 3 , 72 111). J . Jary and M. Marek, Collect. Czech. Chem. , 1 9 8 0 , 4 5 , 3571. S. Hanessian and Y . Guidon, Tetrahedron L e t t . , 1 9 8 0 , 2 1 , 2 3 0 5 . B. H. Lipshutz and J . J . Pegram, Tetrahedron L e t t . , 1 9 8 0 , 2 1 , 3 3 4 3 . R. Toman, V. Kovic'ik, and M. Kubac'kovi, Chem. Zwesti, 1980, 3 4 , 2 2 3 . R. Gigg, J. Chem. , Perkin Trans. 1 , 1980, 7 38. L. R . Orosko and 0. S . Chizhov, Bioorg.

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